VALVOLINE OIL -- ZEREX HD PRECHARGED ANTIFREEZE/COOLANT -- 6850-01-441-3223
===================== Product Identification ===================== Product ID:ZEREX HD PRECHARGED ANTIFREEZE/COOLANT MSDS Date:04/07/1999 FSC:6850 NIIN:01-441-3223 Status Code:A === Responsible Party === Company Name:VALVOLINE OIL Address:3499 DABNEY DRIVE Box:14000 City:LEXINGTON State:KY ZIP:40512 Country:US Info Phone Num:606-357-7847 Emergency Phone Num:1-800-274-5253 Resp. Party Other MSDS Num.:503.0324901-001.002 CAGE:72527 === Contractor Identification === Company Name:MID-ATLANTIC CHEMICAL CORP Address:14240 CHERRY LANE CT Box:City:LAUREL State:MD ZIP:20707 Country:US Phone:301-681-2471 Contract Num:SP0450-00-C-5114 CAGE:0XCN7 Company Name:VALVOLINE OIL CO Address:3499 BLAZER PKY Box:14000 City:LEXINGTON State:KY ZIP:40512 Country:US Phone:606-357-7206 / 800-274-5263 CAGE:72527 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL CAS:107-21-1 RTECS #:KW2975000 = Wt:90. OSHA PEL:50,000 PPM ACGIH TLV:127,000 PPM ACGIH STEL:C127 MG/M3;C50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Minumum % Wt:1. Maxumum % Wt:10. Ingred Name:DIPOTASSIUM PHOSPHATE CAS:7758-11-4 Minumum % Wt:1. Maxumum % Wt:7. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: LIVER, KIDNEYS. ACUTE: EYES: CAN CAUSE EYE IRRITATION. SKIN: MAY CAUSE MILD SKIN IRRITATION. CAN, RARELY, CAUSE ALLERGIC SKIN REACTION. ABSORPTION THROUGH SKIN IS POSSIBLE & MAY ADD TO TOXIC EFFECTS FROM BREATHING OR SWALLOWING. SWALLOWING: SWALLOWING SMALL AMOUNTS IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. SWALLOWING LARGE AMOUNTS MAY CAUSE LIVER, KIDNEY AND BRAIN DAMAGE. INHALATION: BREATHING SMALL AMOUNTS IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE AMOUNTS MAYCAUSE INTESTINAL UPSET, IRRRITATION OF AIRWAYS, CNS DEPRESSION, CYANOSIS, LUNG EDEMA, KIDNEY DAMAGE, LIVER DA MAGE, COMA, POSSIBLE DEATH. Explanation of Carcinogenicity:BASED ON THE AVAILABLE INFORMATION, THIS MATERIAL CANNOT BE CLASSIFIED WITH REGARD TO CARCINOGENICITY. THIS MATERIAL IS NOT LISTED AS A CARCIINOGEN BY IARC, NTP OR OSHA. Effects of Overexposure:EYES: STINGING, TEARING, REDNESS, SWELLING OF EYES. SKIN: REDNESS, BURNING, BLISTERING, SCALING. SWALLOWING: NAUSEA, VOMITING, DIARRHEA, COUGH, GIDDINESS, LIVILINESS, LIGHT-HEADED FEELING, DIZZINESS, DROWSINESS, BLUISH COLORING OF SKIN AND NAILS. Medical Cond Aggravated by Exposure:MAY AGGRAVATE PREEXISTING DISORDERS OF THESE ORGANS: KIDNEY DAMAGE, LIVER DAMAGE.. ======================= First Aid Measures ======================= First Aid:EYES: IF SYMPTOMS DEVELOP, MOVE TO FRESH AIR. FLUSH GENTLY WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART. SEEK IMMEDIATE MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHES. WASH EXP OSED AREA WITH SOAP & WATER. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. SWALLOWING: SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS, NOTHING BY MOUTH. CONTACT PHYSICIAN OR POISON CONT ROL CENTER. DO NOT LEAVE VICTIM UNATTENDED. INHALED: MOVE FROM EXPOSURE & TO FRESH AIR. IF SYMPTOMS PERSIST, GET MEDICAL ATTENTION. IF BREATHING DIFFICULT, GIVE OXYGEN. ===================== Fire Fighting Measures ===================== Flash Point:=121.1C, 250.F Lower Limits:1.7 Upper Limits:15.3 Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:WATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHER. WEAR A SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSU RE DEMAND MODE WITH APPROPRIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PERSONAL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM BECAUSE PRODUCT CAN IGNITE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. PERSONS NOT WEARING PROPER PERSONAL PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL. PREVENT RUN-OFF TO SEWERS, ST REAMS OR OTHER BODIES OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE . DO NOT TRANSFER TO AN UNLABELED CONTAINER. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS PRODUCT RESIDUE. DO NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER (EVEN I F EMPTY). KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. WEAR SAFETY GLASSES OR GOGGLES, RESITANT GLOVES AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED, A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. ENGINEERING OR ADMINISTRAT IVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:NEOPRENE, NITRILE RUBBER, OR POLYVINYL CHLORIDE RESISTANT GLOVES. Eye Protection:CHEMICAL SPLASH GOGGLES. Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS TO PREVENT SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V5 Boiling Pt:=165.6C, 330.F B.P. Text:@760.00 MMHG Decomp Temp:=25.C, 77.F Decomp Text:(1.131 KG-9.415 LBS/GAL) Vapor Pres:18.000 MMHG @ 68.00F Spec Gravity:1.131 @ 77.00F pH:10.0 - 11.0 Evaporation Rate & Reference:N/D Appearance and Odor:GREEN LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HEAT, STRONG ACIDS, STRONG ALKALIES, STRONG BASES, STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS. Conditions to Avoid Polymerization:WILL NOT UNDERGO HARZARDOUS POLYMERIZATION. =================== Toxicological Information =================== Toxicological Information:ETHYLENE GLYCOL (CAS# 107-21-1) HAS CAUSED BIRTH DEFECTS IN CERTAIN LABORATORY ANIMALS WHEN GIVEN ORALLY. ===================== Ecological Information ===================== Ecological:NO DATA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF USED ANTIFREEZE IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT DISCARD INTO STORM SEWERS, SEPTIC SYSTEMS OR ONTO THE GROUND. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED BY 49 CFR. CONTAINER MODE: CASES/SURFACE---NO EXCEPTIONS. RQ QUANTITY: ETHYLENE GLYCOL: 5567 LBS; SODIUM NITRITE: 27027. ===================== Regulatory Information ===================== SARA Title III Information:SARA 302 COMPONENTS: NONE. SECTION 311/312: IMMEDIATE, DELAYED. SARA 313 (40 CFR 370-2): ETHYLENE GLYCOL, CAS# 107-21-1. Federal Regulatory Information:CERCLA RQ: ETHYLENE GLYCOL, 5000 LBS. TSCA: THE INTENTIONAL INGREDIENTS OF THIS PRODUCT AS LISTED. State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE. NEW JERSEY RTK LABEL INFORMATION: ETHYLENE GLYCOL, CAS# 107-21-1. PENNSYLVANIA RTK LABEL INFORMATION: 1,2-ETHANEDIOL: 107-21-1. ETHANOL, 2,2'-OXYBIS, CAS# 111-46-6. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.